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Copper-catalyzed nucleophilic trifluoromethylation of propargylic halides.
Miyake, Yoshihiro; Ota, Shin-ichi; Shibata, Masashi; Nakajima, Kazunari; Nishibayashi, Yoshiaki.
Afiliação
  • Miyake Y; Institute of Engineering Innovation, School of Engineering, The University of Tokyo, Yayoi, Tokyo 113-8656, Japan.
Chem Commun (Camb) ; 49(71): 7809-11, 2013 Sep 14.
Article em En | MEDLINE | ID: mdl-23884450
ABSTRACT
Reactions of propargylic halides with trifluoromethyltrimethylsilane in the presence of a catalytic amount of copper(I) thiophene-2-carboxylate (CuTC) have been found to give the corresponding trifluoromethylated products in good to high yields with a high selectivity.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Cobre Idioma: En Ano de publicação: 2013 Tipo de documento: Article
Texto completo
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PubMed Links
Buscar no Google

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Cobre Idioma: En Ano de publicação: 2013 Tipo de documento: Article