Wheel-shaped nanoscale 3d-4f {Co(II)16Ln(III)24} clusters (Ln = Dy and Gd).
Chem Commun (Camb)
; 49(73): 8081-3, 2013 Sep 21.
Article
em En
| MEDLINE
| ID: mdl-23912749
Two unprecedented wheel-shaped nanoscale clusters {Co(II)16Ln(III)24} (Ln = Dy and Gd), with a diameter and a thickness of 3.0 nm and 2.0 nm, respectively, were obtained from the self-assembly of Co(NO3)2, Ln(NO3)3 and a pyridyl-functionalized ß-diketone ligand. Notably, the gadolinium species exhibited a relatively large magnetocaloric effect.
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01-internacional
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MEDLINE
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En
Ano de publicação:
2013
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Article