Synthesis of an imidazolium phosphanide zwitterion and its conversion into anionic imidazol-2-ylidene derivatives.
Angew Chem Int Ed Engl
; 52(38): 10080-3, 2013 Sep 16.
Article
em En
| MEDLINE
| ID: mdl-23929541
ABSTRACT
Matter of opinion The novel zwitterion 1 has been synthesized and studied theoretically and also converted into anionic NHCs 2. The former can also be described as a phosphinidene adduct of an abnormal N-heterocyclic carbene (1') and, in the same vein, the latter represents a phosphinidene adduct of an anionic N-heterocyclic dicarbene (2').
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Ano de publicação:
2013
Tipo de documento:
Article