Visible-light hypervalent iodide carboxylate photo(trifluoro)methylations and controlled radical polymerization of fluorinated alkenes.
Angew Chem Int Ed Engl
; 52(38): 10027-30, 2013 Sep 16.
Article
em En
| MEDLINE
| ID: mdl-23939987
ABSTRACT
IFAB-ulous trifluoromethylation (CX3COO)2I(III) h (X=F, H) and (CH3COO)3I(V)(C6H4COO) are introduced as CX3·/CX3I precursors for metal-free, visible-light, radical (trifluoro)(iodo)methylations of alkenes, illustrated by their use as photoinitiators for the controlled radical polymerization of vinylidene fluoride with external (I(CF2)6I) and in situ generated (CF3I) iodine chain transfer agents, and for block copolymer synthesis.
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Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Assunto principal:
Ácidos Carboxílicos
/
Alcenos
/
Iodetos
Idioma:
En
Ano de publicação:
2013
Tipo de documento:
Article