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Divergent and efficient syntheses of the Lycopodium alkaloids (-)-lycojaponicumin C, (-)-8-deoxyserratinine, (+)-fawcettimine, and (+)-fawcettidine.
Hou, Si-Hua; Tu, Yong-Qiang; Liu, Lin; Zhang, Fu-Min; Wang, Shao-Hua; Zhang, Xiao-Ming.
Afiliação
  • Hou SH; State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000 (P. R. China).
Angew Chem Int Ed Engl ; 52(43): 11373-6, 2013 Oct 18.
Article em En | MEDLINE | ID: mdl-24000162
Four from one: The four title alkaloids (structures shown in blue box) have been synthesized by using a common versatile intermediate with a 6/5/5 tricyclic skeleton. This tricyclic intermediate could be easily assembled by using an intramolecular carbene addition/cyclization and a Dieckmann condensation/Tsuji-Trost allylation as key steps.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Lycopodium / Alcaloides Idioma: En Ano de publicação: 2013 Tipo de documento: Article

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Lycopodium / Alcaloides Idioma: En Ano de publicação: 2013 Tipo de documento: Article