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Water as an activator for palladium(II)-catalyzed olefin polymerization.
Tao, Wen-Jie; Li, Jun-Fang; Peng, Ai-Qing; Sun, Xiu-Li; Yang, Xiao-Hong; Tang, Yong.
Afiliação
  • Tao WJ; State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, 345 Lingling Lu, Shanghai 200032 (P.R. China), Fax: (+86) 21-54925078.
Chemistry ; 19(41): 13956-61, 2013 Oct 04.
Article em En | MEDLINE | ID: mdl-24038439
By a reasonable combination of the Wacker reaction and olefin polymerization processes, water proves to be an excellent activator for the palladium(II)-catalyzed polymerization of ethylene and it provides a safe, environmental-friendly and handy initiator for olefin polymerization. The activity of the olefin polymerization is comparable to reactions catalyzed by the corresponding alkylated cationic palladium complexes.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2013 Tipo de documento: Article

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2013 Tipo de documento: Article