Surface-induced dechlorination of FeOEP-Cl on Cu(111).
Chemphyschem
; 14(15): 3472-5, 2013 Oct 21.
Article
em En
| MEDLINE
| ID: mdl-24038896
ABSTRACT
To be or not to be chlorinated When octaethylporphyrin iron(III) chloride (FeOEP-Cl) molecules are sublimated onto Cu(111) surfaces, two different molecular species are observed through scanning tunneling microscopy, showing either a protrusion or a depression at the center. In combination with van der Waals-corrected density functional calculations, our experiments reveal that one species corresponds to FeOEP-Cl molecules with the chlorine atom pointing away from the surface, whereas the other species has been dechlorinated.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Ano de publicação:
2013
Tipo de documento:
Article