Synthesis and C2-functionalization of indoles with allylic acetates under rhodium catalysis.

Kim, Mirim; Park, Jihye; Sharma, Satyasheel; Han, Sangil; Han, Sang Hoon; Kwak, Jong Hwan; Jung, Young Hoon; Kim, In Su

Kim, Mirim; Park, Jihye; Sharma, Satyasheel; Han, Sangil; Han, Sang Hoon; Kwak, Jong Hwan; Jung, Young Hoon; Kim, In Su.

Afiliação

Kim M; School of Pharmacy, Sungkyunkwan University, Suwon 440-746, Republic of Korea. insukim@skku.edu.

Org Biomol Chem ; 11(42): 7427-34, 2013 Nov 14.

Article em En | MEDLINE | ID: mdl-24081311

ABSTRACT

ABSTRACT

Tandem rhodium-catalyzed oxidative allylation and annulation of acetanilides with allyl acetate to afford the corresponding indoles are described. In addition, the site-selective C2 allylation, crotylation and prenylation of indoles using allylic acetates under rhodium catalysis are reported.

Assuntos

Acetatos/química; Alcenos/química; Indóis/química; Indóis/síntese química; Ródio/química; Catálise; Técnicas de Química Sintética

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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Ródio / Alcenos / Indóis / Acetatos Idioma: En Ano de publicação: 2013 Tipo de documento: Article

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