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Controlling helical chirality of cobalt complexes by chirality transfer from vicinal diamines.
Seo, Min-Seob; Kim, Kiseong; Kim, Hyunwoo.
Afiliação
  • Seo MS; Department of Chemistry, KAIST, Daejeon 305-701, Korea. hwkim@kaist.edu.
Chem Commun (Camb) ; 49(99): 11623-5, 2013 Dec 25.
Article em En | MEDLINE | ID: mdl-24129791
ABSTRACT
Stereoselective cis-trans isomerism of a Co(III)-N2O2 complex has been achieved by coordinating chiral vicinal diamines. The induced metal-centered helical chirality can be exploited for chirality amplification and asymmetric coordination chemistry.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2013 Tipo de documento: Article
Texto completo
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2013 Tipo de documento: Article