The elusive three-coordinate dicationic hydrido boron complex.

Chen, Wen-Ching; Lee, Ching-Yu; Lin, Bo-Chao; Hsu, Yu-Chen; Shen, Jiun-Shian; Hsu, Chao-Ping; Yap, Glenn P A; Ong, Tiow-Gan

Chen, Wen-Ching; Lee, Ching-Yu; Lin, Bo-Chao; Hsu, Yu-Chen; Shen, Jiun-Shian; Hsu, Chao-Ping; Yap, Glenn P A; Ong, Tiow-Gan.

Afiliação

Chen WC; Institute of Chemistry, Academia Sinica , Nangang, Taipei, Taiwan, Republic of China.

J Am Chem Soc ; 136(3): 914-7, 2014 Jan 22.

Article em En | MEDLINE | ID: mdl-24383448

ABSTRACT

ABSTRACT

The formation of a hitherto unknown three-coordinate dicationic hydrido boron complex is described. Interestingly, supporting ligand carbodicarbene gave unprecedented reaction with BH3 without using more highly electrophilic Lewis acid precursors. Spectroscopic, crystallographic, and computational analysis was performed to understand the electronic features of these species.

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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2014 Tipo de documento: Article

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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2014 Tipo de documento: Article