NHCs catalyzed hydrophosphonylation of α-ketoesters and α-trifluoromethyl ketones.
ScientificWorldJournal
; 2013: 890187, 2013.
Article
em En
| MEDLINE
| ID: mdl-24489517
ABSTRACT
N-Heterocyclic carbenes catalyzed hydrophosphonylation reaction of α-ketoesters and α-trifluoromethyl ketones was developed. Under the catalysis of 10 mol% IPr, α-ketoesters or α-trifluoromethyl ketones reacted with dialkyl phosphites to provide quaternary α-hydroxyphosphonates in good to excellent yield.
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1
Coleções:
01-internacional
Base de dados:
MEDLINE
Assunto principal:
Ésteres
/
Cetonas
Idioma:
En
Ano de publicação:
2013
Tipo de documento:
Article