Cooperative effect of two metals: CoPd(OAc)4-catalyzed C-H amination and aziridination.
Chemistry
; 20(18): 5240-3, 2014 Apr 25.
Article
em En
| MEDLINE
| ID: mdl-24668584
ABSTRACT
The first Co/Pd-cocatalyzed intramolecular C-H amination and aziridination reactions were developed. Sulfamate esters were converted to oxathiazinanes by using CoPd(OAc)4 as catalyst and PhI(OAc)2 as oxidant. The mutual presence of both Co and Pd is crucial for the catalytic activity. This combination of two metals with simple acetate ligands provides an economical alternative to the Rh-catalyzed insertion of nitrenoids into C-H bonds.
Palavras-chave
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Assunto principal:
Paládio
/
Aziridinas
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Cobalto
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Ácido Acético
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Complexos de Coordenação
Idioma:
En
Ano de publicação:
2014
Tipo de documento:
Article