Removal of NO(x) at low temperature over mesoporous alpha-Mn2O3 catalyst.
J Nanosci Nanotechnol
; 14(3): 2527-31, 2014 Mar.
Article
em En
| MEDLINE
| ID: mdl-24745258
ABSTRACT
Low-temperature selective catalytic reduction was carried out over various kinds of manganese oxide (MnOx) catalysts. Mesoporous alpha-Mn2O3, commercial bulk Mn2O3, and Mn/SBA-15 were used as the catalyst. The NOx removal performances of the catalysts were compared. Three different amounts of Mn (5, 10, and 15 wt%) were impregnated on SBA-15 to synthesize Mn/SBA-15. The physical and chemical properties of the catalysts were examined by Brunauer-Emmett-Teller, X-ray diffraction, X-ray photoelectron spectroscopy, and H2-temperature programmed reduction analyses. Of all catalysts examined, mesoporous alpha-Mn2O3 exhibited the highest low-temperature SCR de-NOx efficiency, reaching about 90% at 175 degrees C. This is attributed to strong reducing ability and high oxygen mobility of mesoporous alpha-Mn2O3 and well dispersed Mn2O3 in its mesoporous framework.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Assunto principal:
Óxidos
/
Compostos de Manganês
/
Nitrogênio
/
Óxidos de Nitrogênio
Idioma:
En
Ano de publicação:
2014
Tipo de documento:
Article