Catalytic enantioselective inverse electron demand hetero-Diels-Alder reaction with allylsilanes.
Angew Chem Int Ed Engl
; 53(24): 6131-4, 2014 Jun 10.
Article
em En
| MEDLINE
| ID: mdl-24782343
ABSTRACT
The first diastereo- and enantioselective inverse electron demand hetero-Diels-Alder reaction of ß,γ-unsaturated α-ketoesters with allylsilanes is described. Chiral copper(II) catalysts successfully activate the ß,γ-unsaturated α-ketoesters and promote the reaction with allylsilanes with excellent enantioselectivities. This process represents a new entry to chiral oxanes.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Ano de publicação:
2014
Tipo de documento:
Article