Synthesis of long-sought C66 with exohedral stabilization.
Angew Chem Int Ed Engl
; 53(30): 7853-5, 2014 Jul 21.
Article
em En
| MEDLINE
| ID: mdl-24827119
ABSTRACT
Previously reported fused-pentagon fullerenes stabilized by exohedral derivatization do not share the same cage with those stabilized by endohedral encapsulation. Herein we report the crystallographic identification of (#4348)C66Cl10, which has the same cage as that of previously reported Sc2@C66. According to the geometrical data of (#4348)C66Cl10, both strain relief (at the fused pentagons) and local aromaticity (on the remaining sp(2)-hybrided carbon framework) contribute to the exohedral stabilization of this long-sought 66 carbon atom cage.
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01-internacional
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MEDLINE
Idioma:
En
Ano de publicação:
2014
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Article