Nickel-catalyzed redox-economical coupling of alcohols and alkynes to form allylic alcohols.
J Am Chem Soc
; 136(22): 7797-800, 2014 Jun 04.
Article
em En
| MEDLINE
| ID: mdl-24827475
ABSTRACT
We have developed a redox-economical coupling reaction of alcohols and alkynes to form allylic alcohols under mild conditions. The reaction is redox-neutral as well as redox-economical and thus free from any additives such as a reductant or an oxidant. This atom-economical coupling can be applied for the conversion of both aliphatic and benzylic alcohols to the corresponding substituted allylic alcohols in a single synthetic operation.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Tipo de estudo:
Health_economic_evaluation
Idioma:
En
Ano de publicação:
2014
Tipo de documento:
Article