Dimensionality changes in the solid phase at room temperature: 2D → 1D → 3D evolution induced by ammonia sorption-desorption on zinc phosphates.

ABSTRACT

Two-dimensional zinc phosphate NH4Zn2(PO4)(HPO4) (), via ammonia vapor interaction at room temperature, transforms to a one-dimensional novel compound NH4Zn(NH3)PO4 (). By ammonia desorption (in air at room temperature) transforms to NH4ZnPO4 () with a well-known ABW-zeolitic topology. The crystal structure of was solved ab initio using synchrotron powder X-ray diffraction data (monoclinic, P21/a, a = 16.5227(2) Å, b = 6.21780(8) Å, c = 5.24317(6) Å, ß = 91.000(2)°, Z = 4). The structures of three compounds include extra-framework ammonium cations to the 4-fold coordinated zinc (ZnO4 tetrahedra for and , and ZnO3N tetrahedra for ) and phosphorus (PO4 tetrahedra) with bi-, mono- or three-dimensional linkages, respectively for , or . To our knowledge, the process described here constitutes the first example of dimensionality change in the solid phase promoted by a solid-gas interaction at room temperature in metal phosphates.