Your browser doesn't support javascript.
loading
Copper-catalyzed nucleophilic trifluoromethylation of benzylic chlorides.
Miyake, Yoshihiro; Ota, Shin-ichi; Shibata, Masashi; Nakajima, Kazunari; Nishibayashi, Yoshiaki.
Afiliação
  • Miyake Y; Institute of Engineering Innovation, School of Engineering, The University of Tokyo, Yayoi, Bunkyo-ku, Tokyo, 113-8656, Japan. ynishiba@sogo.t.u-tokyo.ac.jp.
Org Biomol Chem ; 12(30): 5594-6, 2014 Aug 14.
Article em En | MEDLINE | ID: mdl-24968287
Reactions of primary and secondary benzylic chlorides with trifluoromethyltrimethylsilane in the presence of a catalytic amount of copper(i) thiophene-2-carboxylate (CuTC) have been found to give the corresponding benzylic trifluoromethylated products in good to high yields.
Assuntos
Texto completo
Imprimir
XML
PubMed Links
Buscar no Google

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Cobre / Hidrocarbonetos Clorados / Hidrocarbonetos Fluorados Idioma: En Ano de publicação: 2014 Tipo de documento: Article
Texto completo
Imprimir
XML
PubMed Links
Buscar no Google

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Cobre / Hidrocarbonetos Clorados / Hidrocarbonetos Fluorados Idioma: En Ano de publicação: 2014 Tipo de documento: Article