Aerobic Oxidation of Primary Alcohols by a New Mononuclear Cu(II) -Radical Catalyst.
Angew Chem Int Ed Engl
; 38(8): 1095-8, 1999.
Article
em En
| MEDLINE
| ID: mdl-25138506
Primary alcohols such as ethanol or benzyl alcohol are selectively and catalytically oxidized by the mononuclear copper(II) radical complex 1-a functional model of the metalloenzyme galactose oxidase-with oxygen from air at 20°C to give the corresponding aldehydes and H2 O2 in about 60 % yield.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Ano de publicação:
1999
Tipo de documento:
Article