Efficient Mukaiyama aldol reaction in water with TiO4 tetrahedra on a hydrophobic mesoporous silica surface.
Chem Commun (Camb)
; 50(88): 13473-6, 2014 Nov 14.
Article
em En
| MEDLINE
| ID: mdl-25234202
ABSTRACT
A new heterogeneous catalyst, hydrophobic TiO4-deposited mesoporous silica, has been designed for the efficient Mukaiyama-aldol condensation, a water-participating Lewis acid-catalyzed reaction between a hydrophobic carbonyl compound and silyl enol ether. The prepared catalyst suspended in water exhibited high catalytic performance as a reusable catalyst for the reaction without a surfactant.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Ano de publicação:
2014
Tipo de documento:
Article