Rhodium(iii)-catalyzed C-H allylation of electron-deficient alkenes with allyl acetates.
Chem Commun (Camb)
; 51(2): 342-5, 2015.
Article
em En
| MEDLINE
| ID: mdl-25406546
ABSTRACT
Rhodium-catalyzed C-H allylation of acrylamides with allyl acetates is reported. The use of weakly coordinating directing group resulted in high reaction efficiency, broad functionality tolerance and excellent γ-selectivity, which opens a new synthetic pathway for the access of 1,4-diene skeletons.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Assunto principal:
Ródio
/
Acrilamidas
/
Alcenos
/
Compostos Alílicos
/
Acetatos
Idioma:
En
Ano de publicação:
2015
Tipo de documento:
Article