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Communication: Visible line intensities of the triatomic hydrogen ion from experiment and theory.
Petrignani, Annemieke; Berg, Max H; Grussie, Florian; Wolf, Andreas; Mizus, Irina I; Polyansky, Oleg L; Tennyson, Jonathan; Zobov, Nikolai F; Pavanello, Michele; Adamowicz, Ludwik.
Afiliação
  • Petrignani A; Max-Planck-Institut für Kernphysik, Saupfercheckweg 1, D-69117 Heidelberg, Germany.
  • Berg MH; Max-Planck-Institut für Kernphysik, Saupfercheckweg 1, D-69117 Heidelberg, Germany.
  • Grussie F; Max-Planck-Institut für Kernphysik, Saupfercheckweg 1, D-69117 Heidelberg, Germany.
  • Wolf A; Max-Planck-Institut für Kernphysik, Saupfercheckweg 1, D-69117 Heidelberg, Germany.
  • Mizus II; Institute of Applied Physics, Russian Academy of Science, Ulyanov Street 46, Nizhnii Novgorod 603950, Russia.
  • Polyansky OL; Institute of Applied Physics, Russian Academy of Science, Ulyanov Street 46, Nizhnii Novgorod 603950, Russia.
  • Tennyson J; Department of Physics and Astronomy, University College London, London WC1E 6BT, United Kingdom.
  • Zobov NF; Institute of Applied Physics, Russian Academy of Science, Ulyanov Street 46, Nizhnii Novgorod 603950, Russia.
  • Pavanello M; Department of Chemistry, Rutgers University, Newark, New Jersey 07102, USA.
  • Adamowicz L; Department of Chemistry and Biochemistry, The University of Arizona, Tucson, Arizona 85721, USA.
J Chem Phys ; 141(24): 241104, 2014 Dec 28.
Article em En | MEDLINE | ID: mdl-25554125
The visible spectrum of H3(+) is studied using high-sensitivity action spectroscopy in a cryogenic radiofrequency multipole trap. Advances are made to measure the weak ro-vibrational transitions from the lowest rotational states of H3(+) up to high excitation energies providing visible line intensities and, after normalisation to an infrared calibration line, the corresponding Einstein B coefficients. Ab initio predictions for the Einstein B coefficients are obtained from a highly precise dipole moment surface of H3(+) and found to be in excellent agreement, even in the region where states have been classified as chaotic.

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2014 Tipo de documento: Article

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2014 Tipo de documento: Article