Synthesis and properties of arylvinylidene-bridged triphenylamines.
J Org Chem
; 80(4): 2418-24, 2015 Feb 20.
Article
em En
| MEDLINE
| ID: mdl-25603313
ABSTRACT
A series of arylvinylidene-bridged triphenylamines were efficiently synthesized through the thionation/Barton-Kellogg olefination sequence from their corresponding carbonyl precursors. The electrochemical investigations identified these highly distorted scaffolds as fairly strong electron donors capable of several reversible oxidation steps with the first oxidation occurring at a potential comparable to that of ferrocene for the n-hexyl-substituted diphenylvinylidene-bridged compound.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Ano de publicação:
2015
Tipo de documento:
Article