Enhanced CO2 electroreduction efficiency through secondary coordination effects on a pincer iridium catalyst.
Chem Commun (Camb)
; 51(27): 5947-50, 2015 Apr 07.
Article
em En
| MEDLINE
| ID: mdl-25735788
ABSTRACT
An iridium(III) trihydride complex supported by a pincer ligand with a hydrogen bond donor in the secondary coordination sphere promotes the electrocatalytic reduction of CO2 to formate in water/acetonitrile with excellent Faradaic efficiency and low overpotential. Preliminary mechanistic experiments indicate formate formation is facile while product release is a kinetically difficult step.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Ano de publicação:
2015
Tipo de documento:
Article