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Cathodic reductive coupling of methyl cinnamate on boron-doped diamond electrodes and synthesis of new neolignan-type products.
Kojima, Taiki; Obata, Rika; Saito, Tsuyoshi; Einaga, Yasuaki; Nishiyama, Shigeru.
Afiliação
  • Kojima T; Department of Chemistry, Faculty of Science and Technology, Keio University, Hiyoshi 3-14-1 Kohoku-ku, Yokohama 223-8522, Japan.
  • Obata R; Research and Education Center for Natural Sciences, Keio University, Hiyoshi 4-1-1 Kohoku-ku, Yokohama 223-8521, Japan.
  • Saito T; International Institute for Integrative Sleep Medicine, University of Tsukuba, 1-1-1 Tennodai, Tsukuba, Ibaraki 305-8577, Japan ; Japan Science and Technology Agency (JST), CREST, Hiyoshi 3-14-1, Yokohama 223-8522, Japan.
  • Einaga Y; Department of Chemistry, Faculty of Science and Technology, Keio University, Hiyoshi 3-14-1 Kohoku-ku, Yokohama 223-8522, Japan ; Japan Science and Technology Agency (JST), CREST, Hiyoshi 3-14-1, Yokohama 223-8522, Japan.
  • Nishiyama S; Department of Chemistry, Faculty of Science and Technology, Keio University, Hiyoshi 3-14-1 Kohoku-ku, Yokohama 223-8522, Japan ; Japan Science and Technology Agency (JST), CREST, Hiyoshi 3-14-1, Yokohama 223-8522, Japan.
Beilstein J Org Chem ; 11: 200-3, 2015.
Article em En | MEDLINE | ID: mdl-25815070
ABSTRACT
The electroreduction reaction of methyl cinnamate on a boron-doped diamond (BDD) electrode was investigated. The hydrodimer, dimethyl 3,4-diphenylhexanedioate (racemate/meso = 7426), was obtained in 85% yield as the major product, along with small amounts of cyclic methyl 5-oxo-2,3-diphenylcyclopentane-1-carboxylate. Two new neolignan-type products were synthesized from the hydrodimer.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2015 Tipo de documento: Article
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2015 Tipo de documento: Article