The dynamic, size-dependent properties of [5]-[12]cycloparaphenylenes.
Chem Soc Rev
; 44(18): 6401-10, 2015 Sep 21.
Article
em En
| MEDLINE
| ID: mdl-25913289
ABSTRACT
[n]Cycloparaphenylenes (or "carbon nanohoops") are cyclic fragments of carbon nanotubes that consist of n para linked benzene rings. These strained, all sp(2) hybridized macrocycles, have size-dependent optical and electronic properties that are the most dynamic at the smallest size regime where n = 5-12. This review highlights the unique physical phenomena surrounding this class of polycyclic aromatic hydrocarbons, specifically emphasizing the novel structural, optical, and electronic properties of [5]-[12]CPPs.
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01-internacional
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MEDLINE
Idioma:
En
Ano de publicação:
2015
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Article