Rhodium(ii) dimers without metal-metal bonds.
Dalton Trans
; 44(30): 13460-3, 2015 Aug 14.
Article
em En
| MEDLINE
| ID: mdl-26151727
Oxidation of ((Me)BDI)Rh(cyclooctene) ((Me)BDI = [2,6-Me(2)C(6)H(3)NCMe](2)CH) with Br(2) or I(2) produces paramagnetic halide-bridged Rh(II) dimers [((Me)BDI)Rh](2)(µ-X)(2) without a direct Rh-Rh bond. Steric factors are proposed to play a key role in preventing the formation of Rh-Rh bonded alternative structures.
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01-internacional
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MEDLINE
Idioma:
En
Ano de publicação:
2015
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Article