Palladium-Catalyzed Oxalyl Amide Directed Silylation and Germanylation of Amine Derivatives.
Org Lett
; 17(15): 3646-9, 2015 Aug 07.
Article
em En
| MEDLINE
| ID: mdl-26161949
ABSTRACT
Palladium-catalyzed direct ortho-silylation of oxalyl amide-protected phenylmethanamine and phenethylamine with commercially available disilanes is reported. Germanylation products were also produced under the same reaction conditions. This protocol tolerated oxalyl amide-protected aliphatic amines, which gave γ-C-H silylation products.
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Coleções:
01-internacional
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MEDLINE
Idioma:
En
Ano de publicação:
2015
Tipo de documento:
Article