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Palladium N-Heterocyclic Carbene Precatalyst Site Isolated in the Core of a Star Polymer.
Bukhryakov, Konstantin V; Mugemana, Clément; Vu, Khanh B; Rodionov, Valentin O.
Afiliação
  • Bukhryakov KV; KAUST Catalysis Center and Division of Physical Sciences and Engineering, King Abdullah University of Science and Technology , Thuwal 23955-6900, Kingdom of Saudi Arabia.
  • Mugemana C; KAUST Catalysis Center and Division of Physical Sciences and Engineering, King Abdullah University of Science and Technology , Thuwal 23955-6900, Kingdom of Saudi Arabia.
  • Vu KB; KAUST Catalysis Center and Division of Physical Sciences and Engineering, King Abdullah University of Science and Technology , Thuwal 23955-6900, Kingdom of Saudi Arabia.
  • Rodionov VO; KAUST Catalysis Center and Division of Physical Sciences and Engineering, King Abdullah University of Science and Technology , Thuwal 23955-6900, Kingdom of Saudi Arabia.
Org Lett ; 17(19): 4826-9, 2015 Oct 02.
Article em En | MEDLINE | ID: mdl-26397957
ABSTRACT
An approach for supporting a Pd-NHC complex on a soluble star polymer with nanoscale dimensions is described. The resulting star polymer catalyst exhibits excellent activity in cross-coupling reactions, is stable in air and moisture, and is easily recoverable and recyclable. These properties are distinct and unattainable with the small-molecule version of the same catalyst.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2015 Tipo de documento: Article
Texto completo
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2015 Tipo de documento: Article