AIBN/NaBr-promoted aerobic oxidation of benzylic alcohols via a radical process.
Org Biomol Chem
; 14(2): 577-581, 2016 Jan 14.
Article
em En
| MEDLINE
| ID: mdl-26530962
ABSTRACT
An economic and practical AIBN-initiated aerobic oxidation system of benzylic alcohols, hetero aryl alcohols and allyl alcohols was developed for the first time. Moderate to excellent yields were obtained with a broad substrate scope. Moreover, a proposed mechanism of a radical process was assumed and confirmed by the key intermediate detected.
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Coleções:
01-internacional
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MEDLINE
Idioma:
En
Ano de publicação:
2016
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Article