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Porous cationic polymers: the impact of counteranions and charges on CO2 capture and conversion.
Buyukcakir, Onur; Je, Sang Hyun; Choi, Dong Shin; Talapaneni, Siddulu Naiudu; Seo, Yongbeom; Jung, Yousung; Polychronopoulou, Kyriaki; Coskun, Ali.
Afiliação
  • Buyukcakir O; Graduate School of Energy, Environment, Water and Sustainability (EEWS), Korea Advanced Institute of Science and Technology (KAIST), 373-1 Guesong Dong, Daejeon, 305-701, Republic of Korea. coskun@kaist.ac.kr.
  • Je SH; Graduate School of Energy, Environment, Water and Sustainability (EEWS), Korea Advanced Institute of Science and Technology (KAIST), 373-1 Guesong Dong, Daejeon, 305-701, Republic of Korea. coskun@kaist.ac.kr.
  • Choi DS; Graduate School of Energy, Environment, Water and Sustainability (EEWS), Korea Advanced Institute of Science and Technology (KAIST), 373-1 Guesong Dong, Daejeon, 305-701, Republic of Korea. coskun@kaist.ac.kr.
  • Talapaneni SN; Graduate School of Energy, Environment, Water and Sustainability (EEWS), Korea Advanced Institute of Science and Technology (KAIST), 373-1 Guesong Dong, Daejeon, 305-701, Republic of Korea. coskun@kaist.ac.kr.
  • Seo Y; Institute of Basic Science (IBS), KAIST, Daejeon, Republic of Korea.
  • Jung Y; Graduate School of Energy, Environment, Water and Sustainability (EEWS), Korea Advanced Institute of Science and Technology (KAIST), 373-1 Guesong Dong, Daejeon, 305-701, Republic of Korea. coskun@kaist.ac.kr.
  • Polychronopoulou K; Mechanical Engineering, Khalifa University, Abu Dhabi, United Arab Emirates.
  • Coskun A; Graduate School of Energy, Environment, Water and Sustainability (EEWS), Korea Advanced Institute of Science and Technology (KAIST), 373-1 Guesong Dong, Daejeon, 305-701, Republic of Korea. coskun@kaist.ac.kr and Department of Chemistry, KAIST, Daejeon, Republic of Korea.
Chem Commun (Camb) ; 52(5): 934-7, 2016 Jan 18.
Article em En | MEDLINE | ID: mdl-26583526
ABSTRACT
Porous cationic polymers (PCPs) with surface areas up to 755 m(2) g(-1) bearing positively charged viologen units in their backbones and different counteranions have been prepared. We have demonstrated that by simply varying counteranions both gas sorption and catalytic properties of PCPs can be tuned for metal-free capture and conversion of CO2 into value-added products such as cyclic carbonates with excellent yields.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2016 Tipo de documento: Article
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2016 Tipo de documento: Article