Remarkable Lattice Shrinkage in Highly Oriented Crystalline Three-Dimensional Metal-Organic Framework Thin Films.
Inorg Chem
; 54(24): 11593-5, 2015 Dec 21.
Article
em En
| MEDLINE
| ID: mdl-26641131
ABSTRACT
Highly oriented crystalline thin films of metal-organic frameworks (MOFs) have promising practical applications, such as in gas separation, catalysis, and sensing. We report on the successful fabrication of highly oriented crystalline thin films of three-dimensional porous MOFs, Fe(pz)[M(CN)4] (M = Ni, Pd; pz = pyrazine). Synchrotron X-ray diffraction studies reveal not only the highly oriented crystalline nature but also the remarkable shrunken structure of the thin films (â¼3-7% volume shrinkage) compared with bulk samples. Furthermore, because of lattice shrinkage, these films exhibit large lattice expansions upon guest adsorption, in marked contrast to the almost unchanged lattice in the bulk samples.
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01-internacional
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MEDLINE
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En
Ano de publicação:
2015
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Article