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Ion flow in a zeolitic imidazolate framework results in ionic diode phenomena.
Madrid, Elena; Buckingham, Mark A; Stone, James M; Rogers, Adrian T; Gee, William J; Burrows, Andrew D; Raithby, Paul R; Celorrio, Veronica; Fermin, David J; Marken, Frank.
Afiliação
  • Madrid E; Department of Chemistry, University of Bath, Bath BA2 7AY, UK. F.Marken@bath.ac.uk.
  • Buckingham MA; Department of Chemistry, University of Bath, Bath BA2 7AY, UK. F.Marken@bath.ac.uk.
  • Stone JM; Centre for Photonics and Photonic Materials, Department of Physics, University of Bath, Bath BA2 7AY, UK.
  • Rogers AT; Microscopy and Analysis Suite, Department of Physics, University of Bath, Bath BA2 7AY, UK.
  • Gee WJ; Department of Chemistry, University of Bath, Bath BA2 7AY, UK. F.Marken@bath.ac.uk.
  • Burrows AD; Department of Chemistry, University of Bath, Bath BA2 7AY, UK. F.Marken@bath.ac.uk.
  • Raithby PR; Department of Chemistry, University of Bath, Bath BA2 7AY, UK. F.Marken@bath.ac.uk.
  • Celorrio V; School of Chemistry, University of Bristol, Bristol, BS8 1TS, UK.
  • Fermin DJ; School of Chemistry, University of Bristol, Bristol, BS8 1TS, UK.
  • Marken F; Department of Chemistry, University of Bath, Bath BA2 7AY, UK. F.Marken@bath.ac.uk.
Chem Commun (Camb) ; 52(13): 2792-4, 2016 Feb 14.
Article em En | MEDLINE | ID: mdl-26771027
ABSTRACT
Ionic transport (for applications in nanofluidics or membranes) and "ionic diode" phenomena in a zeolitic imidazolate framework (ZIF-8) are investigated by directly growing the framework from aqueous Zn(2+) and 2-methylimidazole as an "asymmetric plug" into a 20 µm diameter pore in a ca. 6 µm thin poly-ethylene-terephthalate (PET) film.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2016 Tipo de documento: Article
Texto completo
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2016 Tipo de documento: Article