Gate-opening effect in ZIF-8: the first experimental proof using inelastic neutron scattering.
Chem Commun (Camb)
; 52(18): 3639-42, 2016 Mar 04.
Article
em En
| MEDLINE
| ID: mdl-26845644
ABSTRACT
The gate-opening phenomenon in ZIFs is of paramount importance to understand their behavior in industrial molecular separations. Here we show for the first time using in situ inelastic neutron scattering (INS) the swinging of the -CH3 groups and the imidazolate linkers in the prototypical ZIF-8 and ZIF-8@AC hybrid materials upon exposure to mild N2 pressure.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Ano de publicação:
2016
Tipo de documento:
Article