Open-Pore Two-Dimensional MFI Zeolite Nanosheets for the Fabrication of Hydrocarbon-Isomer-Selective Membranes on Porous Polymer Supports.
Angew Chem Int Ed Engl
; 55(25): 7184-7, 2016 06 13.
Article
em En
| MEDLINE
| ID: mdl-27101318
ABSTRACT
Two-dimensional zeolite nanosheets that do not contain any organic structure-directing agents were prepared from a multilamellar MFI (ML-MFI) zeolite. ML-MFI was first exfoliated by melt compounding and then detemplated by treatment with a mixture of H2 SO4 and H2 O2 (piranha solution). The obtained OSDA-free MFI nanosheets disperse well in water and can be used for coating applications. Deposits made on porous polybenzimidazole (PBI) supports by simple filtration of these suspensions exhibit an n-butane/isobutane selectivity of 5.4, with an n-butane permeance of 3.5×10(-7) â
mol m(-2) s(-1) Pa(-1) (ca. 1000â
GPU).
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01-internacional
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MEDLINE
Idioma:
En
Ano de publicação:
2016
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Article