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The synthesis of pyrroles and oxazoles based on gold α-imino carbene complexes.
Loy, Nicole S Y; Choi, Subin; Kim, Sunggak; Park, Cheol-Min.
Afiliação
  • Loy NS; Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371, Singapore.
  • Choi S; Department of Chemistry, UNIST (Ulsan National Institute of Science & Technology), Ulsan 44919, Korea. cmpark@unist.ac.kr.
  • Kim S; Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371, Singapore.
  • Park CM; Department of Chemistry, UNIST (Ulsan National Institute of Science & Technology), Ulsan 44919, Korea. cmpark@unist.ac.kr.
Chem Commun (Camb) ; 52(46): 7336-9, 2016 May 31.
Article em En | MEDLINE | ID: mdl-27152984
ABSTRACT
Cationic gold complexes of α-oximimino carbenes have been identified to react with weak nucleophiles including enol ethers and nitriles. These findings allowed us to develop the highly efficient synthesis of pyrroles and oxazoles.

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Tipo de estudo: Prognostic_studies Idioma: En Ano de publicação: 2016 Tipo de documento: Article

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Tipo de estudo: Prognostic_studies Idioma: En Ano de publicação: 2016 Tipo de documento: Article