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High Conductivity in Molecularly p-Doped Diketopyrrolopyrrole-Based Polymer: The Impact of a High Dopant Strength and Good Structural Order.
Karpov, Yevhen; Erdmann, Tim; Raguzin, Ivan; Al-Hussein, Mahmoud; Binner, Marcus; Lappan, Uwe; Stamm, Manfred; Gerasimov, Kirill L; Beryozkina, Tetyana; Bakulev, Vasiliy; Anokhin, Denis V; Ivanov, Dimitri A; Günther, Florian; Gemming, Sibylle; Seifert, Gotthard; Voit, Brigitte; Di Pietro, Riccardo; Kiriy, Anton.
Afiliação
  • Karpov Y; Leibniz-Institut für Polymerforschung Dresden e.V., Hohe Straße 6, Dresden, 01069, Germany.
  • Erdmann T; Leibniz-Institut für Polymerforschung Dresden e.V., Hohe Straße 6, Dresden, 01069, Germany.
  • Raguzin I; Technische Universität Dresden, Center for Advancing Electronics Dresden (cfaed), Dresden, 01062, Germany.
  • Al-Hussein M; Leibniz-Institut für Polymerforschung Dresden e.V., Hohe Straße 6, Dresden, 01069, Germany.
  • Binner M; Physics Department, The University of Jordan, Amman, 11942, Jordan.
  • Lappan U; Leibniz-Institut für Polymerforschung Dresden e.V., Hohe Straße 6, Dresden, 01069, Germany.
  • Stamm M; Leibniz-Institut für Polymerforschung Dresden e.V., Hohe Straße 6, Dresden, 01069, Germany.
  • Gerasimov KL; Leibniz-Institut für Polymerforschung Dresden e.V., Hohe Straße 6, Dresden, 01069, Germany.
  • Beryozkina T; Technische Universität Dresden, Center for Advancing Electronics Dresden (cfaed), Dresden, 01062, Germany.
  • Bakulev V; Faculty of Fundamental Physical and Chemical Engineering, Lomonosov Moscow State University, GSP-1, 1-51 Leninskie Gory, Moscow, 119991, Russia.
  • Anokhin DV; Technology for Organic Synthesis Department, Ural Federal University, Mira str., 28, 620002, Yekaterinburg, Russia.
  • Ivanov DA; Technology for Organic Synthesis Department, Ural Federal University, Mira str., 28, 620002, Yekaterinburg, Russia.
  • Günther F; Faculty of Fundamental Physical and Chemical Engineering, Lomonosov Moscow State University, GSP-1, 1-51 Leninskie Gory, Moscow, 119991, Russia.
  • Gemming S; Institute for Problems of Chemical Physics RAS, Semenov Av. 1, Chernogolovka, Moscow Region, 142432, Russia.
  • Seifert G; Faculty of Fundamental Physical and Chemical Engineering, Lomonosov Moscow State University, GSP-1, 1-51 Leninskie Gory, Moscow, 119991, Russia.
  • Voit B; Institut de Sciences des Matériaux de Mulhouse, CNRS UMR 7361, 15 Jean Starcky, F-68057, Mulhouse, France.
  • Di Pietro R; Technische Universität Dresden, Center for Advancing Electronics Dresden (cfaed), Dresden, 01062, Germany.
  • Kiriy A; Helmholtz-Zentrum Dresden-Rossendorf, Bautzner Landstraße 400, 01328, Dresden, Germany.
Adv Mater ; 28(28): 6003-10, 2016 Jul.
Article em En | MEDLINE | ID: mdl-27172371
[3]-Radialene-based dopant CN6-CP studied herein, with its reduction potential of +0.8 versus Fc/Fc+ and the lowest unoccupied molecular orbital level of -5.87 eV, is the strongest molecular p-dopant reported in the open literature, so far. The efficient p-doping of the donor-acceptor dithienyl-diketopyrrolopyrrole-based copolymer having the highest unoccupied molecular orbital level of -5.49 eV is achieved. The doped films exhibit electrical conductivities up to 70 S cm(-1) .
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2016 Tipo de documento: Article
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2016 Tipo de documento: Article