Chemical potential and entropy in monodisperse and polydisperse hard-sphere fluids using Widom's particle insertion method and a pore size distribution-based insertion probability.
J Chem Phys
; 144(21): 214503, 2016 Jun 07.
Article
em En
| MEDLINE
| ID: mdl-27276959
ABSTRACT
We estimate the excess chemical potential Δµ and excess entropy per particle Δs of computer-generated, monodisperse and polydisperse, frictionless hard-sphere fluids. For this purpose, we utilize the Widom particle insertion method, which for hard-sphere systems relates Δµ to the probability to successfully (without intersections) insert a particle into a system. This insertion probability is evaluated directly for each configuration of hard spheres by extrapolating to infinity the pore radii (nearest-surface) distribution and integrating its tail. The estimates of Δµ and Δs are compared to (and comply well with) predictions from the Boublík-Mansoori-Carnahan-Starling-Leland equation of state. For polydisperse spheres, we employ log-normal particle radii distributions with polydispersities δ = 0.1, 0.2, and 0.3.
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01-internacional
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MEDLINE
Idioma:
En
Ano de publicação:
2016
Tipo de documento:
Article