Towards the total synthesis of keramaphidin B.
Beilstein J Org Chem
; 12: 1096-100, 2016.
Article
em En
| MEDLINE
| ID: mdl-27340496
ABSTRACT
The enantio- and diastereoselective Michael addition of a δ-valerolactone-derived pronucleophile to a substituted furanyl nitroolefin catalysed by a bifunctional cinchonine-derived thiourea has been used as the key stereocontrolling step in a new synthetic strategy to the heavily functionalised piperidine core of keramaphidin B.
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MEDLINE
Idioma:
En
Ano de publicação:
2016
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Article