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Bimetallic MOFs (H3O)x[Cu(MF6)(pyrazine)2]·(4 - x)H2O (M = V4+, x = 0; M = Ga3+, x = 1): co-existence of ordered and disordered quantum spins in the V4+ system.
Manson, Jamie L; Schlueter, John A; Garrett, Kerry E; Goddard, Paul A; Lancaster, Tom; Möller, Johannes S; Blundell, Stephen J; Steele, Andrew J; Franke, Isabel; Pratt, Francis L; Singleton, John; Bendix, Jesper; Lapidus, Saul H; Uhlarz, Marc; Ayala-Valenzuela, Oscar; McDonald, Ross D; Gurak, Mary; Baines, Christopher.
Afiliação
  • Manson JL; Department of Chemistry and Biochemistry, Eastern Washington University, Cheney, WA 99004, USA. jmanson@ewu.edu.
  • Schlueter JA; Materials Science Division, Argonne National Laboratory, Argonne, IL 60439, USA.
  • Garrett KE; Department of Chemistry and Biochemistry, Eastern Washington University, Cheney, WA 99004, USA. jmanson@ewu.edu.
  • Goddard PA; Department of Physics, University of Warwick, Coventry CV4 7AL, UK.
  • Lancaster T; Center for Materials Physics, Durham University, Durham DH1 3LE, UK.
  • Möller JS; Clarendon Laboratory, Department of Physics, University of Oxford, Oxford OX1 3PU, UK.
  • Blundell SJ; Clarendon Laboratory, Department of Physics, University of Oxford, Oxford OX1 3PU, UK.
  • Steele AJ; Clarendon Laboratory, Department of Physics, University of Oxford, Oxford OX1 3PU, UK.
  • Franke I; Clarendon Laboratory, Department of Physics, University of Oxford, Oxford OX1 3PU, UK.
  • Pratt FL; ISIS Pulsed-Muon Facility, STFC Rutherford Appleton Laboratory, Chilton, Oxfordshire OX11 0QX, UK.
  • Singleton J; National High Magnetic Field Laboratory, Los Alamos National Laboratory, Los Alamos, NM 87545, USA.
  • Bendix J; Department of Chemistry, University of Copenhagen, Copenhagen DK-2100, Denmark.
  • Lapidus SH; X-ray Science Division, Advanced Photon Source, Argonne National Laboratory, Lemont IL 60439, USA.
  • Uhlarz M; Hochfeld-Magnetlabor Dresden (HLD-EMFL), Helmholtz-Zentrum Dresden Rossendorf, DE-01314, Dresden, Germany.
  • Ayala-Valenzuela O; National High Magnetic Field Laboratory, Los Alamos National Laboratory, Los Alamos, NM 87545, USA.
  • McDonald RD; National High Magnetic Field Laboratory, Los Alamos National Laboratory, Los Alamos, NM 87545, USA.
  • Gurak M; National High Magnetic Field Laboratory, Los Alamos National Laboratory, Los Alamos, NM 87545, USA.
  • Baines C; Laboratory for Muon-Spin Spectroscopy, Paul Scherrer Institut, CH-5232 Villigen PSI, Switzerland.
Chem Commun (Camb) ; 52(85): 12653-12656, 2016 Oct 18.
Article em En | MEDLINE | ID: mdl-27713934
ABSTRACT
The title compounds are bimetallic MOFs containing [Cu(pyz)2]2+ square lattices linked by MF6n- octahedra. In each, only the Cu2+ spins exhibit long-range magnetic order below 3.5 K (M = V4+) and 2.6 K (M = Ga3+). The V4+ spins remain disordered down to 0.5 K.
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Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2016 Tipo de documento: Article
Buscar no Google
Imprimir
XML
PubMed Links

Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2016 Tipo de documento: Article