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Achiral Inorganic Gypsum Acts as an Origin of Chirality through Its Enantiotopic Surface in Conjunction with Asymmetric Autocatalysis.
Matsumoto, Arimasa; Kaimori, Yoshiyasu; Uchida, Mizuki; Omori, Haruna; Kawasaki, Tsuneomi; Soai, Kenso.
Afiliação
  • Matsumoto A; Department of Applied Chemistry, Tokyo University of Science, Kagurazaka, Shinjuku-ku, Tokyo, 162-8601, Japan.
  • Kaimori Y; Research Institute for Science and Technology, Kagurazaka, Shinjuku-ku, Tokyo, 162-8601, Japan.
  • Uchida M; Department of Applied Chemistry, Tokyo University of Science, Kagurazaka, Shinjuku-ku, Tokyo, 162-8601, Japan.
  • Omori H; Department of Applied Chemistry, Tokyo University of Science, Kagurazaka, Shinjuku-ku, Tokyo, 162-8601, Japan.
  • Kawasaki T; Department of Applied Chemistry, Tokyo University of Science, Kagurazaka, Shinjuku-ku, Tokyo, 162-8601, Japan.
  • Soai K; Research Institute for Science and Technology, Kagurazaka, Shinjuku-ku, Tokyo, 162-8601, Japan.
Angew Chem Int Ed Engl ; 56(2): 545-548, 2017 01 09.
Article em En | MEDLINE | ID: mdl-27906493
ABSTRACT
Achiral inorganic gypsum (CaSO4 ⋅2 H2 O) triggers the asymmetric autocatalysis of pyrimidyl alkanol on its two-dimensional enantiotopic faces to give highly enantioenriched alkanol products with absolute configurations corresponding to the respective enantiotopic surfaces. This is the first example of highly enantioselective synthesis on the enantiotopic surface of an achiral mineral.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2017 Tipo de documento: Article
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2017 Tipo de documento: Article