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The mechanism of activation of amidobenzylidene ruthenium chelates - latent catalysts of olefin metathesis.
Rogalski, Szymon; Zak, Patrycja; Tadeuszyk, Natalia; Pyta, Krystian; Przybylski, Piotr; Pietraszuk, Cezary.
Afiliação
  • Rogalski S; Adam Mickiewicz University in Poznan, Faculty of Chemistry, Umultowska 89b, 61-614 Poznan, Poland. pietrasz@amu.edu.pl.
  • Zak P; Adam Mickiewicz University in Poznan, Faculty of Chemistry, Umultowska 89b, 61-614 Poznan, Poland. pietrasz@amu.edu.pl.
  • Tadeuszyk N; Adam Mickiewicz University in Poznan, Faculty of Chemistry, Umultowska 89b, 61-614 Poznan, Poland. pietrasz@amu.edu.pl.
  • Pyta K; Adam Mickiewicz University in Poznan, Faculty of Chemistry, Umultowska 89b, 61-614 Poznan, Poland. pietrasz@amu.edu.pl.
  • Przybylski P; Adam Mickiewicz University in Poznan, Faculty of Chemistry, Umultowska 89b, 61-614 Poznan, Poland. pietrasz@amu.edu.pl.
  • Pietraszuk C; Adam Mickiewicz University in Poznan, Faculty of Chemistry, Umultowska 89b, 61-614 Poznan, Poland. pietrasz@amu.edu.pl.
Dalton Trans ; 46(4): 1277-1282, 2017 Jan 24.
Article em En | MEDLINE | ID: mdl-28067379
ABSTRACT
Amidobenzylidene ruthenium chelates - latent catalysts of olefin metathesis can be easily activated by the addition of Brønsted or Lewis acids. Their activation in the presence of hydrogen chloride involves the formation of catalytically active trans-dichloro carbamatobenzylidene ruthenium chelates.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2017 Tipo de documento: Article
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2017 Tipo de documento: Article