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Enantioselective Syntheses of Furan Atropisomers by an Oxidative Central-to-Axial Chirality Conversion Strategy.
Raut, Vivek S; Jean, Marion; Vanthuyne, Nicolas; Roussel, Christian; Constantieux, Thierry; Bressy, Cyril; Bugaut, Xavier; Bonne, Damien; Rodriguez, Jean.
Afiliação
  • Raut VS; Aix Marseille Univ , CNRS, Centrale Marseille, iSm2, Marseille, France.
  • Jean M; Aix Marseille Univ , CNRS, Centrale Marseille, iSm2, Marseille, France.
  • Vanthuyne N; Aix Marseille Univ , CNRS, Centrale Marseille, iSm2, Marseille, France.
  • Roussel C; Aix Marseille Univ , CNRS, Centrale Marseille, iSm2, Marseille, France.
  • Constantieux T; Aix Marseille Univ , CNRS, Centrale Marseille, iSm2, Marseille, France.
  • Bressy C; Aix Marseille Univ , CNRS, Centrale Marseille, iSm2, Marseille, France.
  • Bugaut X; Aix Marseille Univ , CNRS, Centrale Marseille, iSm2, Marseille, France.
  • Bonne D; Aix Marseille Univ , CNRS, Centrale Marseille, iSm2, Marseille, France.
  • Rodriguez J; Aix Marseille Univ , CNRS, Centrale Marseille, iSm2, Marseille, France.
J Am Chem Soc ; 139(6): 2140-2143, 2017 02 15.
Article em En | MEDLINE | ID: mdl-28106391
ABSTRACT
For the first time, enantiomerically enriched atropoisomeric furans have been accessed using a central-to-axial chirality conversion strategy. Hence, oxidation of the enantioenriched dihydrofuran precursors gave rise to axially chiral furans with high enantiopurities accounting from excellent conversion percentages (cp) in most cases.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2017 Tipo de documento: Article
Texto completo
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2017 Tipo de documento: Article