Optically Active Cubic Liquid Crystalline Phase Made of Achiral Polycatenar Stilbene Derivatives.

ABSTRACT

Achiral stilbene polycatenars forming smectic, columnar or cubic phase depending on the terminal chains length, were studied. The cubic Im3m phase exhibited optical activity originating in twisted face-to-face molecular aggregates. The optical activity of the phase is preserved upon sample crystallization, providing evidence of a transfer of chirality on a molecular level.