Iridium-Catalyzed Anti-Stereoselective Asymmetric Ring-Opening Reactions of Azabenzonorbornadienes with Carboxylic Acids.
J Org Chem
; 82(6): 3167-3172, 2017 03 17.
Article
em En
| MEDLINE
| ID: mdl-28234001
ABSTRACT
The first anti-stereoselective asymmetric ring-opening reactions of azabenzonorbornadienes with carboxylic acids have been realized with an iridium catalyst assisted by nBu4NBr. The reaction features broad substrate scope and good functional group tolerance and allows the synthesis of chiral dihydronaphthalene derivatives with high optical purities.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Ano de publicação:
2017
Tipo de documento:
Article