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Iridium-Catalyzed Anti-Stereoselective Asymmetric Ring-Opening Reactions of Azabenzonorbornadienes with Carboxylic Acids.
Zhu, Meina; Chen, Jingchao; He, Xiaobo; Gu, Cuiping; Xu, Jianbin; Fan, Baomin.
Afiliação
  • Zhu M; YMU-HKBU Joint Laboratory of Traditional Natural Medicine, and ‡Key Laboratory of Chemistry in Ethnic Medicinal Resources, Yunnan Minzu University , Kunming, Yunnan 650500, People's Republic of China.
  • Chen J; YMU-HKBU Joint Laboratory of Traditional Natural Medicine, and ‡Key Laboratory of Chemistry in Ethnic Medicinal Resources, Yunnan Minzu University , Kunming, Yunnan 650500, People's Republic of China.
  • He X; YMU-HKBU Joint Laboratory of Traditional Natural Medicine, and ‡Key Laboratory of Chemistry in Ethnic Medicinal Resources, Yunnan Minzu University , Kunming, Yunnan 650500, People's Republic of China.
  • Gu C; YMU-HKBU Joint Laboratory of Traditional Natural Medicine, and ‡Key Laboratory of Chemistry in Ethnic Medicinal Resources, Yunnan Minzu University , Kunming, Yunnan 650500, People's Republic of China.
  • Xu J; YMU-HKBU Joint Laboratory of Traditional Natural Medicine, and ‡Key Laboratory of Chemistry in Ethnic Medicinal Resources, Yunnan Minzu University , Kunming, Yunnan 650500, People's Republic of China.
  • Fan B; YMU-HKBU Joint Laboratory of Traditional Natural Medicine, and ‡Key Laboratory of Chemistry in Ethnic Medicinal Resources, Yunnan Minzu University , Kunming, Yunnan 650500, People's Republic of China.
J Org Chem ; 82(6): 3167-3172, 2017 03 17.
Article em En | MEDLINE | ID: mdl-28234001
ABSTRACT
The first anti-stereoselective asymmetric ring-opening reactions of azabenzonorbornadienes with carboxylic acids have been realized with an iridium catalyst assisted by nBu4NBr. The reaction features broad substrate scope and good functional group tolerance and allows the synthesis of chiral dihydronaphthalene derivatives with high optical purities.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2017 Tipo de documento: Article
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2017 Tipo de documento: Article