One-pot controlled synthesis of AuPd@Pd core-shell nanocrystals with enhanced electrocatalytic performances for formic acid oxidation and glycerol oxidation.
J Colloid Interface Sci
; 508: 551-558, 2017 Dec 15.
Article
em En
| MEDLINE
| ID: mdl-28866463
In this work, AuPd@Pd core-shell nanocrystals (AuPd@Pd NCs) were fabricated by a one-pot co-reduction approach, where theophylline-7-acetic acid (TAA) acted asa new structure-directing agent. The crystal structure and composition were mainly characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), high-angle annular dark-field scanning transmission electron microscopy (HAADF-STEM), X-ray diffraction (XRD), together with X-ray photoelectron spectroscopy (XPS). The growth mechanism of AuPd@Pd NCs was investigated in detail. The obtained AuPd@Pd NCs exhibited superior catalytic characters for formic acid oxidation reaction (FAOR) and glycerol oxidation reaction (GOR) in contrast with commercial Pd black in alkaline media.
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01-internacional
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MEDLINE
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En
Ano de publicação:
2017
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Article