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Phosphine-catalyzed enantioselective [3 + 2] cycloadditions of γ-substituted allenoates with ß-perfluoroalkyl enones.
Zhou, Wei; Wang, Huamin; Tao, Mengna; Zhu, Chao-Ze; Lin, Tao-Yan; Zhang, Junliang.
Afiliação
  • Zhou W; Shanghai Key Laboratory of Green Chemistry and Chemical Processes , School of Chemistry and Molecular Engineering , East China Normal University , Shanghai , 200062 , P. R. China . Email: jlzhang@chem.ecnu.edu.cn ; http://faculty.ecnu.edu.cn/s/1811/main.jspy.
  • Wang H; Shanghai Key Laboratory of Green Chemistry and Chemical Processes , School of Chemistry and Molecular Engineering , East China Normal University , Shanghai , 200062 , P. R. China . Email: jlzhang@chem.ecnu.edu.cn ; http://faculty.ecnu.edu.cn/s/1811/main.jspy.
  • Tao M; Shanghai Key Laboratory of Green Chemistry and Chemical Processes , School of Chemistry and Molecular Engineering , East China Normal University , Shanghai , 200062 , P. R. China . Email: jlzhang@chem.ecnu.edu.cn ; http://faculty.ecnu.edu.cn/s/1811/main.jspy.
  • Zhu CZ; Shanghai Key Laboratory of Green Chemistry and Chemical Processes , School of Chemistry and Molecular Engineering , East China Normal University , Shanghai , 200062 , P. R. China . Email: jlzhang@chem.ecnu.edu.cn ; http://faculty.ecnu.edu.cn/s/1811/main.jspy.
  • Lin TY; Shanghai Key Laboratory of Green Chemistry and Chemical Processes , School of Chemistry and Molecular Engineering , East China Normal University , Shanghai , 200062 , P. R. China . Email: jlzhang@chem.ecnu.edu.cn ; http://faculty.ecnu.edu.cn/s/1811/main.jspy.
  • Zhang J; Shanghai Key Laboratory of Green Chemistry and Chemical Processes , School of Chemistry and Molecular Engineering , East China Normal University , Shanghai , 200062 , P. R. China . Email: jlzhang@chem.ecnu.edu.cn ; http://faculty.ecnu.edu.cn/s/1811/main.jspy.
Chem Sci ; 8(6): 4660-4665, 2017 Jun 01.
Article em En | MEDLINE | ID: mdl-28936335
ABSTRACT
The enantioselective construction of densely functionalized cyclopentene bearing contiguous three stereocenters has been a challenging task in organic synthesis. Herein, we present a phoshine-catalyzed highly regio-, diastereo- and enantioselective [3 + 2] cycloaddition of γ-substituted allenoates with ß-perfluoroalkyl enones, delivering a wide range of densely functionalized perfluoroalkylated cyclopentenes with three contiguous chiral stereocenters.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2017 Tipo de documento: Article
Texto completo
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Ano de publicação: 2017 Tipo de documento: Article