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Distal radical migration strategy: an emerging synthetic means.
Li, Weipeng; Xu, Wentao; Xie, Jin; Yu, Shouyun; Zhu, Chengjian.
Afiliação
  • Li W; State Key Laboratory of Coordination Chemistry, Jiangsu Key Laboratory of Advanced Organic Materials, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, P. R. China. xie@nju.edu.cn yushouyun@nju.edu.cn cjzhu@nju.edu.cn.
Chem Soc Rev ; 47(3): 654-667, 2018 Feb 05.
Article em En | MEDLINE | ID: mdl-29177314
The remote radical migration strategy has gained considerable momentum. During the past three years, we have witnessed the rapid development of sustainable and practical C-C and C-H bond functionalization by means of long-distance 1,n-radical migration (n = 4, 5, 6) events. Its advent brings our chemical community a new platform to deal with the challenging migration transformations and thus complements the existing ionic-type migration protocols. In this review, the recent achievements in distal radical migration triggered C-C and C-H bond functionalization are summarized.

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Tipo de estudo: Guideline Idioma: En Ano de publicação: 2018 Tipo de documento: Article

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Tipo de estudo: Guideline Idioma: En Ano de publicação: 2018 Tipo de documento: Article