Microporous Cobalt(II)-Organic Framework with Open O-Donor Sites for Effective C2H2 Storage and C2H2/CO2 Separation at Room Temperature.
Inorg Chem
; 56(24): 14767-14770, 2017 Dec 18.
Article
em En
| MEDLINE
| ID: mdl-29215270
ABSTRACT
The self-assembly of a bifunctional organic ligand with a formate-bridged rod-shaped secondary building unit leads to a new microporous metal-organic framework (MOF). This MOF shows a moderately high C2H2 storage capacity (145 cm3/g) and an excellent adsorption selectivity for C2H2/CO2 (11) at room temperature. Furthermore, its discriminatory sorption behavior toward C2H2 and CO2 was probed by computational analysis in detail.
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01-internacional
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MEDLINE
Idioma:
En
Ano de publicação:
2017
Tipo de documento:
Article