Dentritic platinum-palladium/palladium core-shell nanocrystals/reduced graphene oxide: One-pot synthesis and excellent electrocatalytic performances.
J Colloid Interface Sci
; 514: 93-101, 2018 Mar 15.
Article
em En
| MEDLINE
| ID: mdl-29245076
ABSTRACT
Herein, we developed a facile one-pot co-reduction method to fabricate highly dentritic platinum-palladium/palladium core-shell nanocrystals on reduced graphene oxide (PtPd@Pd NCs/rGO), where poly-l-lysine (PLL) worked as the eco-friendly structure director and stabilizer. The nanocomposite was mainly characterized by microscopic analysis, X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), and thermogravimetric analysis (TGA), along with the discussion of the formation mechanism. The synthesized PtPd@Pd NCs/rGO have the enlarged electrochemically active surface area (ECSA) of 51.65â¯m2â¯g-1, showing 1.3 folds enhancement in the peak current density relative to commercial Pt/C (50â¯wt%) for glycerol oxidation reaction (GOR), coupled with the small Tafel slope of 28â¯mVâ¯dec-1 for hydrogen evolution reaction (HER).
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01-internacional
Base de dados:
MEDLINE
Idioma:
En
Ano de publicação:
2018
Tipo de documento:
Article